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[1]张中华,金士威*,段晶明,等.台州电子废物拆解地区表层土壤中酞酸酯的污染水平[J].武汉工程大学学报,2010,(07):28-32.[doi:10.3969/j.issn.16742869.2010.07.007]
　ZHANG Zhong hua,JIN Shi wei,DUAN Jing ming,et al.Phthalates levels in soil samples from the Ewaste disassembly sites[J].Journal of Wuhan Institute of Technology,2010,(07):28-32.[doi:10.3969/j.issn.16742869.2010.07.007]
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台州电子废物拆解地区表层土壤中酞酸酯的污染水平(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2010年07期
页码:
28-32
栏目:
资源与土木工程
出版日期:
2010-07-31

文章信息/Info

Title:

Phthalates levels in soil samples from the Ewaste disassembly sites
文章编号:
16742869(2010)07002805
作者:
张中华1; 2; 金士威1*; 段晶明1; 黎明1; 黄艳1
1.武汉工程大学化工与制药学院，绿色化工过程省部共建教育部重点实验室，湖北 武汉 430074；
2.浙江省台州市环境科学设计研究院，浙江 台州 318000
Author(s):
ZHANG Zhonghua1; 2; JIN Shiwei1; DUAN Jingming1; LI Ming1; HUANG Yan1

(1.School of Chemical Engineering and Pharmacy,Wuhan Institute of Technology,Key Laboratory for
Green Chemical Process of Ministry of Education, Wuhan 430074，China;
2.Institute of Environmental Science and Engineering Design，Taizhou 318000,China)
关键词:
电子废物; 土壤; 酞酸酯; 色谱质谱联用技术
Keywords:
Ewaste; soil; phthalate esters (PAEs); gas chromatographmass spectrometry (GCMS)
分类号:
X83
DOI:
10.3969/j.issn.16742869.2010.07.007
文献标志码:
A
摘要:
采用气相色谱-质谱联用的方法，研究了浙江台州电子废物拆解地区表层土壤样品中邻苯二甲酸二甲酯(DMP)、邻苯二甲酸二丁酯(DBP)、邻苯二甲酸丁基苄基酯(BBP)、邻苯二甲酸二乙酯(DEP)、邻苯二甲酸二(2-乙基己基)酯(DEHP) 、邻苯二甲酸二正辛酯(DOP)等6种酞酸酯污染物(PAEs).结果表明：在拆解点附近100 m内，6种PAEs化合物的总含量(ΣPAEs)为9.11～50.58 mg·kg-1，离拆解点1 000 m处，ΣPAEs为2.63～17.55 mg·kg-1.对照点ΣPAEs为低于检测限(nd)～7.15 mg·kg-1.DEHP和DBP是电子废物拆解地区主要的酞酸酯污染物.分析结果表明：浙江台州电子废物拆解地区表层土壤受到了严重的PAEs污染.
Abstract:
Phthalate esters (PAEs) including dimethyl phthalate (DMP),dibutyl phthalate (DBP),butylbenzyl phthalate (BBP),diethyl phthalate (DEP),bis(2ethylhexyl) phthalate (DEHP) and dioctyl phthalate (DOP) were determined by gas chromatograph–mass spectrometry (GCMS) method in the surface soils of Ewaste disassembly sites in Taizhou city,Zhejiang Province.The result showed that the total PAEs concentrations (ΣPAEs) ranged from 9.11 to 50.58 mg·kg-1 and 2.63 to 17.55 mg·kg-1 near 100 m and 1000 m in the Ewaste disassembly sites respectively.The ΣPAEs ranged from not detected (nd) to 7.15 mg·kg-1 in control site.DEHP and DBP were the major phthalates accounting for more than 90% of total phthalates studied.The data suggested the surface soils of Ewaste disassembly sites in Taizhou were severely contaminated by PAEs.

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备注/Memo

备注/Memo:
20100510基金项目：湖北省自然科学基金（2006ABA284）作者简介：张中华(1978)，男，浙江台州人，工程师.研究方向：环境影响评价.
*通信联系人：金士威，副教授，博士.研究方向：环境监测与生态毒理学.
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