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[1]周红,王怡宁,潘志权,等.非均相催化氧化合成葡萄糖醛酸及内酯的研究进展[J].武汉工程大学学报,2012,(4):1-5.
 ZHOU Hong,WANG Yi\|ning,PAN Zhi\|quan,et al.Research progress on synthesis of glucuronic acid and glucurolactone byheterogeneous catalytic oxidation[J].Journal of Wuhan Institute of Technology,2012,(4):1-5.
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2012年4期
页码:
1-5
栏目:
化学与化学工程
出版日期:
2012-05-30

文章信息/Info

Title:
Research progress on synthesis of glucuronic acid and glucurolactone by
heterogeneous catalytic oxidation
文章编号:
16742869(2012)04000105
作者:
周红王怡宁 潘志权黄齐茂
武汉工程大学化工与制药学院,湖北 武汉 430074
Author(s):
ZHOU HongWANG Yi\|ningPAN Zhi\|quanHUANG Qi\|mao
School of Engineering &Phamacy, Wuhan Institute of Technology, Wuhan 430074, China
关键词:
葡萄糖醛酸及内酯非均相催化氧化合成
Keywords:
glucuronic acid and glucurolactone heterogeneous catalytic oxidation synthesis
分类号:
TQ464.54
DOI:
-
文献标志码:
AAdoi:103969/jissn16742869201204001
摘要:
对葡醛内酯的性质、用途及各种合成葡醛内酯方法进行了介绍和评述,综合比较其它催化过程,非均相催化氧化具有工艺过程简单、三废少及催化剂可回收利用等优点;从催化剂组成、合成反应条件及收率综述了不同载体负载催化剂非均相催化氧化合成葡醛酸及内酯的方法,分别介绍了以铂、钯、钌、氧化铬、2,2,6,6-四甲基-1-哌啶为催化剂的催化氧化过程.非均相催化氧化在葡醛酸及内酯的合成中具有潜在研究、开发及应用价值.
Abstract:
The properties, application and synthesis methods of glucurolactone were introduced and reviewed. Compared with other catalysis processes, heterogeneous catalysis oxidation methods have simple process engieering, less pollution and high recycle rate and other merits,and the methods in preparing glucuronic acid and glucurolactone were summarized according to the compositions, catalytic synthesis reaction conditions and yields; the catalytic oxidation using Pt, Pd, CrO3, Ru and 2,2,6,6\|tetramethy 1\|1\|piperdinyloxy as catalysts was introduced. We can conclude that heterogeneous catalysis oxidation has potential value in research, development as well as application in the synthesis of glucuronic acid and glucurolactone.

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