|本期目录/Table of Contents|

[1]李庆祥,向爱华,孟祥高.1, 4二(对甲苯磺酰基)1, 4, 7三氮环壬烷的结构[J].武汉工程大学学报,2012,(10):46-49.[doi:103969/jissn16742869201210011]
　LI Qing xiang,XIANG Ai hua,MENG Xiang gao.Synthesis and crystal structure of 1, 2bis (ptolysulfonyl)1,4,7triazacyclononane[J].Journal of Wuhan Institute of Technology,2012,(10):46-49.[doi:103969/jissn16742869201210011]
点击复制

1, 4二(对甲苯磺酰基)1, 4, 7三氮环壬烷的结构(/HTML)
分享到：

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2012年10期
页码:
46-49
栏目:
化学与化学工程
出版日期:
2012-11-06

文章信息/Info

Title:
Synthesis and crystal structure of 1, 2bis (ptolysulfonyl)1,4,7
triazacyclononane
文章编号:
16742869(2012)10004604
作者:
李庆祥1;  向爱华1;  孟祥高2
1. 武汉工程大学绿色化工过程教育部重点实验室, 湖北省新型反应器与绿色化学工艺重点实验室,
湖北 武汉 430074; 2. 华中师范大学化学学院, 湖北 武汉 430079
Author(s):
LI Qingxiang1;  XIANG Aihua1;  MENG Xianggao2
1.Key Laboratory for Green Chemical Process of Ministry of Education and Hubei Key Laboratory of Novel
Chemical Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430074, China;
2.College of Chemistry Huazhong Normal University, Wuhan 430079, China
关键词:
1;  4;  7三氮环壬烷; 对甲苯磺酰基; 配合物; 晶体结构
Keywords:
1; 4; 7triazacyclononane ;  ptolysulfonyl;  complex;  crystal structure
分类号:
O623.42+6.1
DOI:
103969/jissn16742869201210011
文献标志码:
A
摘要:
为了合理设计和修饰1, 4, 7三氮环壬烷配体以得到有特殊性质的功能配合物，合成了一个修饰1, 4, 7三氮环壬烷的重要中间体化合物 1, 4二(对甲苯磺酰基)1, 4, 7三氮环壬烷, 并用X射线晶体衍射的方法测定了该化合物的结构. 结果表明，该化合物晶体属正交晶系, 空间群为Pbcn, a=0.572 15(7) nm, b=1.373 74(17) nm, c=2.741 9(3) nm, V=2.155 1(5) nm3, Z=4, Mr=437.57, F(000)=928, Dc=1.349 g/cm3, μ(MoKα) = 0.710 73 mm-1, R=0.084 4 , wR= 0.236 6.其中1 890个独立衍射点, 1 100个I>2σ(I)的可观察衍射点用于结构分析和结构修正. 从晶体结构图可知, 在此化合物中, 两个苯环之间的二面角为37.1°，分子间通过C-H…O氢键进行堆积.
Abstract:
A key intermediate compound which modified 1, 4, 7triazacyclononane 1, 2bis(ptolysulfonyl)1,4,7triazacyclononane was synthesized and characterized by Xray structure determination. The result shows that this compound crystallizes in the Orthorhombic space group Pbcn with a=0.572 15(7), b=1.373 74(17), c=2.741 9(3) nm, α=β=γ= 90.00°, V=2.155 1(5) nm3, Z=4, Mr=437.57, F(000)=928, Dc=1.349 g/cm3, μ(MoKα)=0.710 73 mm-1, the final R= 0.084 4 and wR=0.236 6 for 1 890 unique reflections with 1 103 observed ones (I>2σ(I)). In the title compound, the dihedral angle between the two benzene rings is 37.1°. The crystal packing is dominated by C—H…O hydrogen bonds between organic molecules.

参考文献/References:

［1］张瑀健, 何振峰, 李国文. 含氮杂冠醚和核酸碱基双亲聚合物的合成及性能\[J\]. 高等学校化学学报, 2010, 31 :14561460.
［2］王翀之, 冯喜梅, 侍孟璐, 等. 1, 4, 7三氮环壬烷衍生物铜、锌配合物切割DNA及催化对硝基苯磷酸单酯水解\[J\]. 无机化学学报, 2012, 28: 839845.
［3］Hirohama T, Arii H, Chikira M. Effect of a conjugated acridine moiety on the binding and reactivity of Cu(II)\[9acridinylmethyl1,4,7triazacyclononane\] with DNA\[J\]. Inorg Biochem, 2004, 98: 17781786.
［4］Shi P F, Jiang Q, Lin J, et al. Gold(III) compounds of 1, 4, 7triazacyclononane showing high cytotoxicity against A549 and HCT116 tumor cell lines\[J\]. Inorg Biochem, 2006,100 : 939945.
［5］Zhang Z，Geng Z R，Kan X W，et al．Iron(III)， nickel(II) and cadmium(II) complexes of triazamacrocyclic ligand with pendant nitrile groups 1，4，7tris(cyanomethyl)1，4，7triazacyclononane: Synthesis， structural characteristics and artificial nuclease activity\[J\]．Inorg Chim Acta，2010，363：18051812．
［6］Wainwright K P. Synthetic and structural aspects of the chemistry of saturated polyaza macrocyclic ligands bearing pendant coordinating groups attached to nitrogen\[J\]. Coord Chem Rev, 1997, 166: 3590.
［7］Schlager O, Wieghardt K, Nuber B. Trivalent Transition Metal Complexes \[MⅢ(L3H)\] (M = Fe,Co) of the Triply Deprotonated Hexadentate Ligand 1,4,7Tris (oaminobenzyl) 1,4,7 triazacyclononane(L) Crystal Structure of \[MnⅣ(L3H)\]BPh4\[J\]. Inorg Chem, 1995, 34: 64566462.
［8］李庆祥, 沈云军, 孟祥高. 1亚甲基苯并咪唑1, 4, 7三氮环壬烷配体及其铜配合物\[Cu(C14H21N5)Br\]2 ·\[CuBr4\]的合成与晶体结构\[J\]. 化学学报, 2008,66:266270.
［9］Richman J E, Atkins T J. Nitrogen analogs of crown ethers\[J\]. J Am Chem Soc,1974,96(7):22682270.
［10］栾锋平, 向爱华, 李庆祥.双核铜配合物的结构和SOD活性及电化学性质\[J\]. 武汉工程大学学报, 2011, 33 : 1215.
［11］Sessler J L, Sibert J W, Lynch V. Model studies related to hemerythrin. Synthesis and characterization of a bridged tetranuclear iron(III) complex\[J\]. Inorg Chem,1990,29: 41434146.
［12］Sheldrick G M. SHELXTL V5.1 Software Reference Manual, Bruker AXS\[M\].Wisconsin: Inc, Madison,1997.

相似文献/References:

[1]栾锋平,向爱华,李庆祥*.双核铜配合物的结构和SOD活性及电化学性质[J].武汉工程大学学报,2011,(09):12.
　LUAN Fengping,XIANG Aihua,LI Qingxiang*.Structure and superoxide dismutase activity and electrochemicalproperty of binuclear copper(II) complex[J].Journal of Wuhan Institute of Technology,2011,(10):12.
[2]冯菊红,丁涛,荣霞,等.1,3,5三嗪类衍生物的合成及其杀菌活性[J].武汉工程大学学报,2013,(04):35.[doi:103969/jissn16742869201304008]
　FENG Ju hong,DING Tao,RONG Xia,et al.Synthesis and fungicidal activity of novel 1,3,5triazine derivatives[J].Journal of Wuhan Institute of Technology,2013,(10):35.[doi:103969/jissn16742869201304008]
[3]彭永利,罗灿,陈柏光.1,3二溴2,2二（溴甲基）丙烷的合成及结构表征[J].武汉工程大学学报,2013,(07):37.[doi:103969/jissn16742869201307008]
　PENG Yong li,LUO Can,CHEN Bai guang.Synthesis and structure characterization of 1,3dibromo2,2Bis(bromomethyl) propane[J].Journal of Wuhan Institute of Technology,2013,(10):37.[doi:103969/jissn16742869201307008]
[4]巨修练,胡成.1,3,4-噁二唑-2-硫酮衍生物的合成及工艺[J].武汉工程大学学报,2014,(01):37.
　JU Xiu-lian,HU Cheng.Synthesis of 1,3,4-oxadiazole-2-thione derivatives[J].Journal of Wuhan Institute of Technology,2014,(10):37.
[5]巨修练,胡成.1,3,4噁二唑2硫酮衍生物的合成及工艺[J].武汉工程大学学报,2014,(02):6.[doi:103969/jissn16742869201402002]
　JU Xiu lian,HU Cheng.Synthesis of 1,3,4oxadiazole2thione derivatives[J].Journal of Wuhan Institute of Technology,2014,(10):6.[doi:103969/jissn16742869201402002]
[6]彭永利,陈柏光,罗灿,等.1,3二溴2,2二(溴甲基)丙烷的量子化学[J].武汉工程大学学报,2014,(04):27.[doi:103969/jissn16742869201404006]
　PENG Yong li,CHEN Bai guang,LUO Can,et al.Quantum chemisty of pentaerythrityl tetrabromide[J].Journal of Wuhan Institute of Technology,2014,(10):27.[doi:103969/jissn16742869201404006]
[7]张　琪,陶世鹏,马　姗,等.新型异喹啉衍生物的合成[J].武汉工程大学学报,2016,38(4):327.[doi:10. 3969/j. issn. 1674?2869. 2016. 04. 003]
　ZHANG Qi,TAO Shipeng,MA Shan,et al.Synthesis of Novel Isoquinoline Derivative[J].Journal of Wuhan Institute of Technology,2016,38(10):327.[doi:10. 3969/j. issn. 1674?2869. 2016. 04. 003]
[8]付晓滨,陈云舟,李　欢,等.5-苯基-2H-1，2，3-三唑-4-羧酸的合成[J].武汉工程大学学报,2016,38(06):527.[doi:10. 3969/j. issn. 1674-2869. 2016. 06. 003]
　FU Xiaobin,CHEN Yunzhou,LI Huan,et al.Synthesis of 5-phenyl-2H-1，2，3-triazole-4-carboxylic acid[J].Journal of Wuhan Institute of Technology,2016,38(10):527.[doi:10. 3969/j. issn. 1674-2869. 2016. 06. 003]
[9]梅　杰１,田回香１,夏语嫣,等.丙二胺铜配合物的合成、晶体结构和热稳定性[J].武汉工程大学学报,2019,(01):19.[doi:10. 3969/j. issn. 1674?2869. 2019. 01. 003]
　MEI Jie,TIAN Huixiang,XIA Yuyan,et al.Synthesis, Crystal Structure and Thermal Stability of Copper Complex of 1,3-Propane Diamine[J].Journal of Wuhan Institute of Technology,2019,(10):19.[doi:10. 3969/j. issn. 1674?2869. 2019. 01. 003]
[10]向春鹏,李宇昊,杜治平*.碳酸丙烯酯的La修饰羟基磷灰石催化尿素醇解法合成[J].武汉工程大学学报,2019,(02):109.[doi:10. 3969/j. issn. 1674?2869. 2019. 02.]
　XIANG Chunpeng,LI Yuhao,DU Zhiping*.Synthesis of Propylene Carbonate from Alcoholysis of Urea Catalyzed by La-Modified Hydroxyapatites[J].Journal of Wuhan Institute of Technology,2019,(10):109.[doi:10. 3969/j. issn. 1674?2869. 2019. 02.]

备注/Memo

备注/Memo:
收稿日期：20120923基金项目：湖北省教育厅科学技术研究项目（D20111501）; 国家自然科学基金资助项目（20571058）作者简介：李庆祥（1964），男，湖北松滋人，教授,博士,硕士研究生导师．研究方向：生物无机化学和有机合成化学．
更新日期/Last Update: