|本期目录/Table of Contents|

[1]陈玉婷,汪苏平,程文翰,等.一种新型罗丹明B类Fe3+荧光探针的合成及性能[J].武汉工程大学学报,2018,40(05):524-529.[doi:10. 3969/j. issn. 1674-2869. 2018. 05. 009]
　CHEN Yuting,WANG Suping,CHENG Wenhan,et al.Synthesis and Properties of Novel Rhodamine B-Based Fe3+ Fluorescent Probe[J].Journal of Wuhan Institute of Technology,2018,40(05):524-529.[doi:10. 3969/j. issn. 1674-2869. 2018. 05. 009]
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一种新型罗丹明B类Fe3+荧光探针的合成及性能(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
40
期数:
2018年05期
页码:
524-529
栏目:
材料科学与工程
出版日期:
2018-12-27

文章信息/Info

Title:
Synthesis and Properties of Novel Rhodamine B-Based Fe3+ Fluorescent Probe
文章编号:
20180509
作者:
陈玉婷; 汪苏平; 程文翰; 曾小平; 郑华明; 吴江渝*
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
CHEN Yuting;  WANG Suping;  CHENG Wenhan;  ZENG Xiaoping;  ZHENG Huaming;  WU Jiangyu*
School of Materials Science and Engineering，Wuhan Institute of Technology，Wuhan 430205， China
关键词:
罗丹明B; 苯甲醛; 铁离子; 荧光探针; 特异性识别
Keywords:
Rhodamine B;  benzaldehyde;  Fe3+;  fluorescent probe;  specific sensing
分类号:
TB34
DOI:
10. 3969/j. issn. 1674-2869. 2018. 05. 009
文献标志码:
A
摘要:
以罗丹明B （RhB）、水合肼、苯甲醛为原料，通过两步反应合成了一种新型罗丹明B类荧光探针RhB-P，并利用傅里叶红外变换光谱与核磁共振氢谱对RhB-P的分子结构进行表征。紫外-可见光谱和荧光光谱表明：在V（乙腈）∶V（水）=1∶1溶液中，RhB-P对Fe3+具有良好的选择性，溶液可从无色转变至粉色。荧光滴定实验以及Job’s 实验结果表明：络合物中n（RhB-P）∶n（Fe3+）=1∶1，且络合物的荧光强度在c（Fe3+）为0.1 μmol/L~20 μmol/L区间范围内，与其呈正线性关系，检出限为0.193 μmol/L。
Abstract:
A novel Rhodamine B-derived fluorescent probe （RhB-P） was synthesized through two steps with Rhodamine B，hydrazine hydrate and benzaldehyde as the raw materials. Fourier-transform infrared spectroscopy and 1H-nuclear magnetic resonance spectroscopy were utilized to investigate the chemical structure of RhB-P. UV-vis and fluorescence spectroscopy demonstrated that the probe RhB-P recognized Fe3+ with high selectivity in the V（acetonitrile）∶V（H2O） =1∶1 solvent， and the colorless solution turned into the pink one. Meanwhile，the fluorescence titration and Job’s plot revealed that RhB-P combined with Fe3+ into a stable chelate complex of n（RhB-P）∶n（Fe3+）=1∶1，and the fluorescent intensity of the complex solution displayed a positive linear relationship with Fe3+ concentration in the range of 0.1 μmol/L to 20 μmol/L with 0.193 μmol/L of detection limit.

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备注/Memo

备注/Memo:
收稿日期：2018-04-13基金项目：武汉工程大学研究生教育创新基金（CX2015004）作者简介：陈玉婷，硕士研究生。E-mail：[email protected]*通讯作者：吴江渝，博士，教授。E-mail：[email protected]引文格式：陈玉婷，汪苏平，程文翰，等. 一种新型罗丹明B类Fe3+荧光探针的合成及性能［J］. 武汉工程大学学报，2018，40（5）：524-529.
更新日期/Last Update: 2018-10-23