|本期目录/Table of Contents|

[1]李　阳,邱唯楚,蔡　卓,等.聚吡咯/石墨烯复合水凝胶的制备与性能[J].武汉工程大学学报,2018,40(05):530-533.[doi:10. 3969/j. issn. 1674-2869. 2018. 05. 010]
　LI Yang,QIU Weichu,CAI Zhuo,et al.Preparation and Properties of Polypyrrole/Graphene Compoiste Hydrogels[J].Journal of Wuhan Institute of Technology,2018,40(05):530-533.[doi:10. 3969/j. issn. 1674-2869. 2018. 05. 010]
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聚吡咯/石墨烯复合水凝胶的制备与性能(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
40
期数:
2018年05期
页码:
530-533
栏目:
材料科学与工程
出版日期:
2018-12-27

文章信息/Info

Title:
Preparation and Properties of Polypyrrole/Graphene Compoiste Hydrogels
文章编号:
20180510
作者:
李　阳; 邱唯楚; 蔡　卓; 申小松; 喻湘华; 李　亮*
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
LI Yang; QIU Weichu; CAI Zhuo; SHEN Xiaosong; YU Xianghua; LI Liang*
School of Materials Science and Engineering，Wuhan Institute of Technology， Wuhan 430205， China
关键词:
聚吡咯; 石墨烯; 水凝胶; 超级电容器
Keywords:
polypyrrole; graphene; hydrogel; supercapacitor
分类号:
O633
DOI:
10. 3969/j. issn. 1674-2869. 2018. 05. 010
文献标志码:
A
摘要:
先通过软模板法制备具有纳米管状结构的聚吡咯（PPy），再以此PPy与氧化石墨烯（GO）为前驱物，通过水热法制备具有三维结构的聚吡咯/石墨烯（PG）复合水凝胶。研究了PPy用量对复合水凝胶的影响。利用扫描电子显微镜对其形貌进行表征，用循环伏安法和恒电流充放电法对复合凝胶的电化学性能进行了研究。结果表明，当m（PPy）∶m（GO）在1.5∶1到2.5∶1之间时，可以形成完整的PG复合水凝胶，复合水凝胶可承受自身重量约1 000倍的压力。PG复合水凝胶具有良好的电化学性能，当恒电流充放电测试的电流密度增加到20 A/g时，复合水凝胶的比电容仍然大于400 F/g。这些结果表明PG复合水凝胶在超级电容器领域有着较好的应用前景。
Abstract:
To fabricate polypyrrole/graphene（PG） composite with three-dimensional network，polypyrrole（PPy） nanotubes prepared by soft template and graphene oxide（GO） were used as precursors，then PG composite hydrogels were synthesized by hydrothermal method. The effects of the amount of PPy on the fabrication of composited hydrogel were studied. The morphology of the composite hydrogels were characterized by scanning electron microscopy，and its electrochemical properties were investigated by cyclic voltammetry and galvanostatic charge-discharge tests. When the mass ratio of PPy to GO was in the range of 1.5∶1 to 2.5∶1，the regular PG composite hydrogels were obtained which could hold a stuff as high as about 1 000 times of its own weight，and also showed excellent electrochemical performance with more than 400 F/g of specific capacitance at 20 A/g of current density in the galvanostatic charge-discharge test. The results indicated that the PG composite hydrogels might be promising material in the application of supercapacitor electrode.

参考文献/References:

［1］　QIN M M，JI W，FENG Y Y，et al. Transparent conductive graphene films prepared by hydroiodic acid and thermal reduction［J］. Chinese Physics B，2014，23（2）：028103（1）-208103（5）. ［2］　XIONG D B，LI X F，BAI Z M，et al. Superior cathode performance of nitrogen-doped grapheme frameworks for lithium ion batteries［J］. ACS Applied Materials & Interfaces，2017，9（12）：10643-10651. ［3］　BERGER C，SONG Z M，LI X B，et al. Electronic confinement and coherence in patterned epitaxial graphene［J］. Science，2006，312（5777）：1191-1196. ［4］　朱芬，张新敏，佘潇，等. 氮掺杂石墨烯凝胶的制备与表征［J］. 武汉工程大学学报，2016，38（3）：259-262. ［5］　SAPURINA I， LI Y，ALEKSEEVA E，et al. Polypyrrole nanotubes： the tuning of morphology and conductivity［J］. Polymer，2017，113：247-258. ［6］　ZHOU X，MA P P，WANG A Q，et al. Dopamine fluorescent sensors based on polypyrrole/graphene quantum dots core/shell hybrids［J］. Biosensors & Bioelectronics，2015，64：404-410. ［7］　NGUYEN D N，YOON H. Recent advances in nanostructured conducting polymers：from synthesis to practical applications［J］. Polymers，2016，8（4）：8040118（1）-8040118（38）. ［8］　ABDELHAMID M E，O’MULLANE A P，SNOOK G A. Storing energy in plastics：a review on conducting polymers & their role in electrochemical energy storage［J］. RSC Advances，2015，5（15）：11611-11626. ［9］　YANG H， QIU Y B， GUO X P. Effects of PPy，GO and PPy/GO composites on the negative plate and on the high-rate partial-state-of-charge performance of lead-acid batteries［J］. Electrochimica Acta，2016，215：346-356. ［10］　LIU Y H，XU K，ZHANG X C，et al. Electrochemical codeposition of graphene/polypyrrole composites on carbon paper for electrochemical capacitors［J］. Current Applied Physics，2016，16（5）：520-526. ［11］　NIRANJANMURTHI L，YEONG-SOON G，KWONTAEK L. Synthesis of reduced graphene oxide/polypyrrole conductive composites［J］. Molecular Crystals & Liquid Crystals，2013，585（1）：60-66. ［12］　YU C F，MA P P，ZHOU X，et al. All-solid-state flexible supercapacitors based on highly dispersed polypyrrole nanowire and reduced graphene oxide composites［J］. ACS Applied Materials & Interfaces，2014，6（20）：17937-17943. ［13］　ZHANG J T，CHEN P，OH B H，et al. High capacitive performance of flexible and binder-free graphene-polypyrrole composite membrane based on in situ reduction of graphene oxide and self-assembly［J］. Nanoscale，2013，5（20）：9860-9866. ［14］　ZHANG F，XIAO F，DONG Z H，et al. Synthesis of polypyrrole wrapped graphene hydrogels composites as supercapacitor electrodes［J］. Electrochimica Acta，2013，114：125-132. ［15］　FAN Z M， ZHU J P， SUN X H， et al. High density of free-standing holey graphene/PPy films for superior volumetric capacitance of supercapacitors［J］. ACS Applied Materials & Interfaces，2017，9（26）：21763-21772. ［16］　李亮，陈旭，艾建连. 偶氮染料掺杂聚吡咯纳米/微米结构材料的制备［J］. 武汉工程大学学报，2013，35（4）：55-60. ［17］　朱珍妮，熊惠之，喻湘华，等. 氮掺杂石墨烯/聚苯胺复合凝胶的制备与性能［J］. 武汉工程大学学报，2016，39（5）：455-460. ［18］　LI L Y， XIA K Q， LI L， et al. Fabrication and characterization of free-standing polypyrrole/graphene oxide nanocomposite paper［J］. Journal of Nanoparticle Research，2012，14（6）：908（1）-908（8）.

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备注/Memo

备注/Memo:
收稿日期：2018-03-06基金项目：武汉工程大学第九届研究生教育创新基金（CX2017018）；2017年地方高校国家级大学生创新创业训练计划项目（201710490004）作者简介：李　阳，硕士研究生。E-mail： [email protected]*通讯作者：李　亮，博士，教授。E-mail： [email protected]引文格式：李阳，邱唯楚，蔡卓，等. 聚吡咯/石墨烯复合水凝胶的制备与性能［［J］. 武汉工程大学学报，2018，40（5）：530-533.
更新日期/Last Update: 2018-10-23