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[1]李 能,曾宪兵,陈怡君,等.新型二维材料MXene及MBene合成的研究进展[J].武汉工程大学学报,2023,45(01):15-24.[doi:10.19843/j.cnki.CN42-1779/TQ.202011010]
 LI Neng,ZENG Xianbin,CHEN Yijun,et al.Progress in Synthesis of New Two-Dimensional Materials:MXene and MBene[J].Journal of Wuhan Institute of Technology,2023,45(01):15-24.[doi:10.19843/j.cnki.CN42-1779/TQ.202011010]
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新型二维材料MXene及MBene合成的研究进展(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
45
期数:
2023年01期
页码:
15-24
栏目:
综述
出版日期:
2023-02-28

文章信息/Info

Title:
Progress in Synthesis of New Two-Dimensional Materials:MXene and MBene
文章编号:
1674 - 2869(2023)01 - 0015 - 10
作者:
李 能12曾宪兵1陈怡君1吴 婧3
1. 硅酸盐建筑材料国家重点实验室(武汉理工大学),湖北 武汉 430070;
2. 武汉工程大学化学与环境工程学院,湖北 武汉 430205;
3. 武汉工程大学邮电与信息学院,湖北 武汉 430074
Author(s):
LI Neng12ZENG Xianbin1CHEN Yijun 1WU Jing3
1. State Key Laboratory of Silicate Materials for Architectures of Wuhan University of Technology, Wuhan 430070, China;
2. School of Chemistry and Environmental Engineering, Wuhan Institute of Technology,Wuhan 430205, China;
3. The College of Post and Telecommunication of Wuhan Institute of Technology,Wuhan 430074, China
关键词:
二维材料MXeneMBene环境与能源材料合成
Keywords:
two-dimensional materials MXene MBene environmental and energy materials synthesis
分类号:
TQ127
DOI:
10.19843/j.cnki.CN42-1779/TQ.202011010
文献标志码:
A
摘要:
科研人员不断在探索关于MXene和MBene材料的合成方法,相继提出了合成MXene更加可靠、安全、绿色的方法,并开创了使用有机溶剂制备MXene的制备方式,但是,关于MBene实验合成的报道少有,根据第一性原理的计算结果已经表明化学方法刻蚀的可行性。综述了近几年来二维过渡金属MXene和MBene合成的研究进展,对不同元素的二维过渡金属MXene介绍了与其相适应的合成方法,也对插层剥离进行了简单的介绍;对于未来MXene及MBene的合成和应用发展提出了展望。认为合成结构优异稳定的MXene及MBene是将其发展为应用的前提;相信随着研究的深入和合成技术在材料研究领域的快速发展,更多具有良好稳定性的MXene及MBene将会被设计和合成出来,二维材料家族将会进一步得到发展。

Abstract:
For exploring synthetic methods for MXene and MBene materials,the safer,greener and more reliable methods for synthesizing MXene have been proposed,and the preparation method of MXene using an organic solvent was pioneered. However,there are few reports on the synthesis of MBene experiments,and the feasibility of chemical etching was confirmed based on first-principles calculations. This article mainly reviews the research progress of two-dimensional transition metal MXene and MBene synthesis in recent years. The two-dimensional transition metal MXene with different elements was introduced to the corresponding synthetic method,and the intercalation stripping was also briefly introduced. Prospects for the future development and application of MXene and MBene were presented. We confirm that the excellent and stable synthetic structure of MXene and MBene is the premise of their development into application. We believe that with the deepening of research and the rapid development of synthetic technology in the field of material research,more MXene and MBene with good stability will be designed and synthesized,and the two- dimensional material family will be further developed.

参考文献/References:

[1] TAN C L, CAO X H,WU X J, et al. Recent advances in ultrathin two-dimensional nanomaterials[J]. Chemical Reviews,2017,117(9):6225-6331.

[2] NAGUIB M, KURTOGLU M, PRESSER V, et al. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2 [J]. Advanced Materials,2011,23(37):4248-4253.
[3] BARSOUM M W. The Mn+1AnN phases:a new class of solids:thermodynamically stable nanolaminates [J]. Progress in Solid State Chemistry,2000,28(1/2/3/4):201-281.
[4] SUN Z M,MUSIC D,AHUJA R,et al. Bonding and classification of nanolayered ternary carbides [J]. Physical Review B,2004,70(9):092102:1-3.
[5] NAGUIB M,MOCHALIN V N, BARSOUM M W,et al. 25th anniversary article:MXenes:a new family of two-dimensional materials [J]. Advanced Materials,2014,26(7):992-1005.
[6] LIM K P G, SHEIKHIREV M, WYATT B C, et al. Fundamentals of MXene synthesis [J].Nature Synthesis, 2022, 1(8): 601-614.
[7] CHEN X Z, KONG Z Z, LI N, et al. Proposing the prospects of Ti3CN transition metal carbides (MXenes) as anodes of Li-ion batteries:a DFT study [J]. Physical Chemistry Chemical Physics,2016,18(48):32937-32943.
[8] MASHTALIR O, COOK K M, MOCHALIN V N,et al. Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media [J]. Journal of Materials Chemistry A,2014,2(35):14334-14338.
[9] RAN J R, GAO G P, LI F T,et al. Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production [J]. Nature Communications,2017,8:13907:1-10.
[10] LI N,CHEN X Z,ONG W J,et al. Understanding of electrochemical mechanisms for CO2 capture and conversion into hydrocarbon fuels in transition-metal carbides (MXenes) [J]. ACS Nano,2017,11(11):10825-10833.
[11] HU M M, LI Z J, HU T,et al. High-capacitance mechanism for Ti3C2Tx MXene by in situ electrochemical Raman spectroscopy investigation [J]. ACS Nano,2016,10(12):11344-11350
[12] LUKATSKAYA M R,BAK S M,YU X Q,et al. Probing the mechanism of high capacitance in 2D titanium carbide using in situ X-ray absorption spectroscopy [J]. Advanced Energy Materials,2015,5(15):1500589:1-4.
[13] HAN M K, YIN X W, WU H, et al. Ti3C2 MXenes with modified surface for high-performance electromagnetic absorption and shielding in the X-band [J]. ACS Applied Materials & Interfaces,2016,8(32):21011-21019.
[14] GHIDIU M,HALIM J,KOTA S,et al. Ion-exchange and cation solvation reactions in Ti3C2 MXene [J]. Chemistry of Materials,2016,28(10):3507-3514.
[15] NAGUIB M,MASHTALIR O,CARLE J,et al. Two-dimensional transition metal carbides [J]. ACS Nano,2012,6(2):1322-1331.
[16] GHIDIU M, NAGUIB M, SHI C, et al. Synthesis and characterization of two-dimensional Nb4C3 (MXene) [J]. Chemical Communications,2014,50(67):9517-9520.
[17] MASHTALIR O,LUKATSKAYA M R,ZHAO M Q,et al. Amine-assisted delamination of Nb2C MXene for Li-ion energy storage devices [J]. Advanced Materials,2015,27(23):3501-3506.
[18] GHIDIU M,LUKATSKAYA M R,ZHAO M Q,et al. Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance [J]. Nature,2014,516(7529):78-81.
[19] CHEN W F,SASAKI K, MA C, et al. Hydrogen-evolution catalysts based on non-noble metal nickel-molybdenum nitride nanosheets [J]. Angewandte Chemie (International Edition),2012,51(25):6131-6135.
[20] CAO B F, VEITH G M, NEUEFEIND J C, et al. Mixed close-packed cobalt molybdenum nitrides as non-noble metal electrocatalysts for the hydrogen evolution reaction [J]. Journal of the American Chemical Society,2013,135(51):19186-19192.
[21] CHEN W F, MUCKERMAN J T, FUJITA E. Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts [J]. Chemical Communications,2013,49(79):8896-8909.
[22] VRUBEL H, HU X L. Molybdenum boride and carbide catalyze hydrogen evolution in both acidic and basic solutions [J]. Angewandte Chemie (International Edition),2012,51(51):12703-12706.
[23] NATU V,PAI R,SOKOL M,et al. 2D Ti3C2Tz MXene synthesized by water-free etching of Ti3AlC2 in Polar organic solvents [J]. Chem,2020,6(3):616-630.
[24] BARSOUM M W,EL-RAGHY T,FARBER L,et al. The topotactic transformation of Ti3SiC2 into a partially ordered cubic Ti ?(C0.67Si0.06)? phase by the diffusion of Si into molten cryolite [J]. Journal of the Electrochemical Society,1999,146(10):3919-3923.
[25] ANASORI B, LUKATSKAYA M R,GOGOTSI Y. 2D metal carbides and nitrides (MXenes) for energy storage [J]. Nature Reviews Materials,2017,2(2):16098:1-17.
[26] NAGUIB M, UNOCIC R R, ARMSTRONG B L, et al. Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes” [J]. Dalton Transactions,2015,44(20):9353-9358.
[27] JIANG Q, KURRA N, ALHABEB M, et al. All pseudocapacitive MXene-RuO2 asymmetric supercapacitors [J]. Advanced Energy Materials,2018,8(13):1703043:1-10.
[28] NAGUIB M,CUME J,DYATKIN B,et al. MXene:a promising transition metal carbide anode for lithium-ion batteries [J]. Electrochemistry Communications,2012,16(1):61-64.
[29] ZHAO L,DONG B L,LI S Z,et al. Inter diffusion reaction-assisted hybridization of two-dimensional metal-organic frameworks and Ti3C2Tx nanosheets for electrocatalytic oxygen evolution[J]. ACS Nano,2017,11(6):5800-5807.
[30] LU C B,TRANCA D,ZHANG J,et al. Molybdenum carbide-embedded nitrogen-doped porous carbon nanosheets as electrocatalysts for water splitting in alkaline media [J]. ACS Nano,2017,11(4):3933-3942.
[31] GAO G P, O’MULLANE A P, DU A J. 2D MXenes:a new family of promising catalysts for the hydrogen evolution reaction [J]. ACS Catalysis,2017,7(1):494-500.
[32] LING C Y,SHI L,OUYANG Y X,et al. Transition metal-promoted V2CO2 (MXenes):a new and highly active catalyst for hydrogen evolution reaction [J]. Advanced Science,2016,3(11):1600180:1-7.
[33] MA L,TING L R L,MOLINARI V,et al. Efficient hydrogen evolution reaction catalyzed by molybdenum carbide and molybdenum nitride [J]. Journal of Materials Chemistry A,2015,3(16):8361-8368.
[34] MASHTALIR O,NAGUIB M, MOCHALIN V N,et al. Intercalation and delamination of layered carbides and carbonitrides [J]. Nature Communications,2013,4:1716:1-7.
[35] LIU Y,ZHANG X F,DONG S L,et al. Synthesis and tribological property of Ti3C2Tx nanosheets [J]. Journal of Materials Science,2017,52(4):2200-2209.
[36] HALIM J,LUKATSKAYA M R,COOK K M,et al. Transparent conductive two-dimensional titanium carbide epitaxial thin films [J]. Chemistry of Materials,2014,26(7):2374-2381.
[37] ALHABEB M, MALESKI K, ANASORI B, et al. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene)[J]. Chemistry of Materials,2017,29(18):7633-7644.
[38] BARSOUM M W,GOLCZEWSKI J,SEIFERT H J,et al. Fabrication and electrical and thermal properties of Ti2InC,Hf2InC and (Ti,Hf)2InC [J]. Journal of Alloys and Compounds,2002,340(1/2):173-179.
[39] EL-RAGHY T,BARSOUM M W,SIKA M. Reaction of Al with Ti3SiC2 in the 800-1 000 ℃ temperature range [J]. Materials Science and Engineering:A,2001,298(1/2):174-178.
[40] LU J ,KOTA S, BARSOUM M W, et al. Atomic structure and lattice defects in nanolaminated ternary transition metal borides [J]. Materials Research Letters,2017,5(4):235-241.
[41] CHAI P,STOIAN S A,TAN X Y,et al. Investigation of magnetic properties and electronic structure of layered-structure borides AlT2B2 (T=Fe,Mn,Cr) and AlFe2-xMnxB2 [J]. Journal of Solid State Chemistry,2015,224:52-61.
[42] BAI Y L, QI X X,DUFF A, et al. Density functional theory insights into ternary layered boride MoAlB [J]. Acta Materialia,2017,132:69-81.
[43] TAN X Y, CHAI P, THOMPSON C M, et al. Magnetocaloric effect in AlFe2B2:toward magnetic refrigerants from earth-abundant elements [J]. Journal of the American Chemical Society,2013,135(25):9553-9557.
[44] KOTA S,AGNE M,ZAPATA-SOLVAS E,et al. Elastic properties,thermal stability,and thermodynamic parameters of MoAlB [J]. Physical Review B,2017,95:144108:1-11.
[45] BARSOUM M W. MAX phases: properties of machinable ternary carbides and nitrides [M]. Weinheim,Germany:Wiley-VCH Verlag GmbH & Co. KGaA,2013:1-12,16.
[46] URBANKOWSKI P, ANASORI B,MAKARYAN T,et al. Synthesis of two-dimensional titanium nitride Ti4N3 (MXene) [J]. Nanoscale,2016,8(22):11385-11391.
[47] LEI J C,ZHANG X,ZHOU Z. Recent advances in MXene:preparation,properties,and applications [J]. Frontiers of Physics,2015,10(3):107307:1-11.
[48] ZHANG T, PAN L M, TANG H, et al. Synthesis of two-dimensional Ti3C2Tx MXene using HCl+LiF etchant:enhanced exfoliation and delamination [J]. Journal of Alloys and Compounds,2017,695:818-826.
[49] AL BALUSHI Z Y, WANG K, GHOSH R K, et al. Two-dimensional gallium nitride realized via graphene encapsulation [J]. Nature Materials,2016,15:1166-1171.
[50] HONG W C, WYATT B C, NEMANI S K, et al.Double transition-metal MXenes: atomistic design of two-dimensional carbides and nitrides[J]. MRS Bulletin,2020,45 (10):850-861.
[51] SOUNDIRARAJU B, GEORGE B K. Two-dimensional titanium nitride (Ti2N) MXene:synthesis,characterization,and potential application as surface-enhanced Raman scattering substrate [J]. ACS Nano,2017,11(9):8892-8900.
[52] ZHOU J, ZHA X H, ZHOU X B,et al. Synthesis and electrochemical properties of two-dimensional hafnium carbide [J]. ACS Nano,2017,11(4):3841-3850.
[53] XIAO X, YU H M, YIN H Y, et al. Salt-templated synthesis of 2D metallic MoN and other nitrides [J]. ACS Nano,2017,11(2):2180-2186.
[54] XIAO X, SONG H B, LI S Z, et al. Scalable salt-templated synthesis of two-dimensional transition metal oxides [J]. Nature Communications,2016,7:11296:1-8.
[55] ADE M, HILLEBRECHT H. Ternary borides Cr2AlB2,Cr3AlB4,and Cr4AlB6:the first members of the series (CrB2)nCrAl with n =1,2,3 and a unifying concept for ternary borides as MAB-phases [J]. Inorganic Chemistry,2015,54(13):6122-6135.
[56] BAI Y L,QI X X,HE X D,et al. Phase stability and weak metallic bonding within ternary‐layered borides CrAlB,Cr2AlB2,Cr3AlB4 and Cr4AlB6 [J]. Journal of the American Ceramic Society,2019,102(6):3715-3727.
[57] GUO Z L,ZHOU J,SUN Z M. New two-dimensional transition metal borides for Li ion batteries and electrocatalysis [J]. Journal of Materials Chemistry A,2017,5(45):23530-23535.
[58] ZHANG H M, XIANG H M, DAI F Z, et al. First demonstration of possible two-dimensional MBene CrB derived from MAB phase Cr2AlB2 [J]. Journal of Materials Science & Technology,2018,34(11):2022-2026.
[59] LIN Z J, ZHOU Y C, LI M S, et al. In-situ hot pressing/solid-liquid reaction synthesis of bulk Cr2AlCZ [J]. Zeitschrift für Metallkunde,2005,96(3):291-296.
[60] FORSYTHE R. Synthesis, characterization, and exfoliation of ternary layered borides [D]. California:UC Riverside,2018.

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备注/Memo

备注/Memo:
收稿日期:2020-11-05
基金项目:教育部霍英东青年教师基金(161008);湖北省杰出青年基金(2020CFA087);深圳市科创委面上项目(JCYJ20190809120015163)
作者简介:李 能,博士,教授。E-mail:[email protected]
引文格式:李能,曾宪兵,陈怡君,等. 新型二维材料MXene及MBene的合成的研究进展[J]. 武汉工程大学学报,2023,45(1):15-24.

更新日期/Last Update: 2023-03-14