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[1]邓 霞,付浚榕,向 珍,等.基于PDMS改性的超疏水织布及其油水分离性能研究[J].武汉工程大学学报,2023,45(05):543-548.[doi:10.19843/j.cnki.CN42-1779/TQ.202307007]
 DENG Xia,FU Junrong,XIANG Zhen,et al.PDMS-Modified Superhydrophobic Fabric and ItsOil-Water Separation Performance[J].Journal of Wuhan Institute of Technology,2023,45(05):543-548.[doi:10.19843/j.cnki.CN42-1779/TQ.202307007]
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基于PDMS改性的超疏水织布及其
油水分离性能研究
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
45
期数:
2023年05期
页码:
543-548
栏目:
生物与环境工程
出版日期:
2023-11-17

文章信息/Info

Title:
PDMS-Modified Superhydrophobic Fabric and Its
Oil-Water Separation Performance
文章编号:
1674 - 2869(2023)05 - 0543 - 06
作者:
邓 霞付浚榕向 珍蔡 思金士威*
中南民族大学化学与材料科学学院,催化转化与能源材料化学教育部重点实验室,
催化材料科学湖北省重点实验室,湖北 武汉 430074
Author(s):
DENG Xia FU Junrong XIANG Zhen CAI Si JIN Shiwei*
Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education, Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry & Materials Science, South-Central Minzu University, Wuhan 430074, China
关键词:
油水分离聚二甲基硅氧烷分离效率超疏水织布
Keywords:
oil-water separation polydimethylsiloxane separation efficiency superhydrophobic fabric

分类号:
TB306; O644.1
DOI:
10.19843/j.cnki.CN42-1779/TQ.202307007
文献标志码:
A
摘要:
含油废水的大量产生造成严重的环境污染,实现含油废水的高效油水分离引起社会的广泛关注。超疏水材料作为一种新型材料,对水和油的润湿性相反,具有高效分离油水污染物的能力。基于聚二甲基硅氧烷(PDMS)改性的方法制备了多功能性的超疏水织布。在紫外光[365 nm,(5.0±0.6) mW·cm-2]条件下,将化学性质稳定、机械性能良好的PDMS接枝到P25型二氧化钛钠米颗粒(P25 NPs)上,制备了无机-有机结合的超疏水涂层,将制备的涂层用于织布改性。改性织布具有超疏水性,能有效地分离油水混合物,分离效率大于99%,表现出良好的分离性能。将改性织布经过100次砂纸摩擦,100 h高温(150 ℃)处理,100 h低温(-20 ℃)处理以及紫外光照射100 h后也依然表现出稳定的超疏水性及油水分离效率。

Abstract:
The large-scale generation of oily wastewater often leads to serious environmental pollution, and effective separation of oil and water in oil-water mixtures has attracted widespread attention.?As a new type of material, superhydrophobic materials have the ability to efficiently separate oil-water pollutants due to their opposite wetting properties towards water and oil. In this study, a multifunctional superhydrophobic fabric was prepared based on the modification of polydimethylsiloxane (PDMS). Under ultraviolet light (365 nm, 5.0 ±0.6 mW·cm-2) conditions, an inorganic-organic superhydrophobic coating was prepared by grafting PDMS with stable chemical properties and excellent mechanical properties onto P25 type titanium dioxide nanoparticles (P25 NPs). The prepared coating was then used for fabric modification, which endowed the fabric with superhydrophobic properties. The modified fabric could be used for the separation of oil-water mixture. The separation efficiency is higher than 99%, exhibiting excellent separation performance. The modified fabric still maintains stable superhydrophobicity and oil-water separation efficiency even after undergoing 100 cycles of sandpaper friction, 100 h of high-temperature treatment (150 ℃), 100 h of low-temperature treatment (- 20 ℃) and 100 h of ultraviolet light irradiation.

参考文献/References:

[1] XIAO F, ZHANG H X, WU T Z, et al. Superhydrophobic/superlipophilic interface layer for oil-water separation[J]. Process Safety and Environmental Protection, 2022, 161: 13-21.

[2] LIAO X F, LI H Q, ZHANG L, et al. Superhydrophobic mGO/PDMS hybrid coating on polyester fabric for oil/water separation[J]. Progress in Organic Coatings, 2018, 115: 172-180.
[3] 楚诗妤,郑志皓,何承珂,等.氧化硅/聚四氟乙烯疏水海绵的制备[J].武汉工程大学学报,2021,43(2):170-173.
[4] 陶先露,杨玉明,黎明,等.仿纳米布沙漠甲壳虫的绿色环保型水收集材料[J].武汉工程大学学报,2021,43(2):174-179.
[5] 廖腾飞,苏春平,卢潼,等.贵金属涂层超亲水-超疏水转化研究[J].武汉工程大学学报,2022,44(6):624-628.
[6] VASQUEZ L, DAVIS A, GATTO F, et al. Multifunctional PDMS polyHIPE filters for oil-water separation and antibacterial activity[J]. Separation and Purification Technology, 2021, 255: 1-11.
[7] HE Z K, YANG X C, MU L P, et al. A versatile “3M” methodology to obtain superhydrophobic PDMS-based materials for antifouling applications[J]. Frontiers in Bioengineering and Biotechnology, 2022, 10: 1-20.
[8] 胡铭杰,孙立,吴子晔,等.聚二甲基硅氧烷-聚丙烯酸甲酯半互穿聚合物网络结构渗透汽化膜的制备及性能[J].化学与生物工程,2019,36(10):41-46.
[9] YANG J X, YANG X Y, JIA Y, et al. Facile synthesis of superhydrophobic MS/TiO2/PDMS sponge for efficient oil-water separation[J]. Water Science and Technology, 2021, 84 (8): 2040-2056.
[10] KIM J, KUMAR U P, LEE S J, et al. Implementation of endurable superhydrophobic surfaces through dilution rate control of the PDMS coating on micro-nano surface structures[J]. Polymer, 2023, 275:1-8.
[11] 陈宋辉,史淑芳.TiO2/CNT催化剂的制备及其光催化性能研究[J].化学与生物工程,2022,39(3):56-59.
[12] ZHOU Q Y, TAKITA R, IKUNO T. Improving the performance of a triboelectric nanogenerator by using an asymmetric TiO2/PDMS composite layer[J]. Nanomaterials, 2023, 13 (5): 832-845.
[13] ZHU X T, ZHANG Z Z, YANG J, et al. Facile fabrication of a superhydrophobic fabric with mechanical stability and easy-repairability[J]. Journal of Colloid and Interface Science, 2012, 380: 182-186.

相似文献/References:

备注/Memo

备注/Memo:
收稿日期:2023-07-03
基金项目:中央高校基本科研业务费专项资金(CZY19005)
作者简介:邓 霞,硕士研究生。E-mail:[email protected]
*通讯作者:金士威,博士,教授。E-mail:[email protected]
引文格式:邓霞,付浚榕,向珍,等. 基于PDMS改性的超疏水织布及其油水分离性能研究[J]. 武汉工程大学学报,2023,45(5):543-548.
更新日期/Last Update: 2023-10-25