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[1]张云飞,徐贵祥,刘　辉,等.2，4，6-三羟甲基苯酚钠改性脲醛树脂的制备与表征[J].武汉工程大学学报,2016,38(3):263-267.[doi:10. 3969/j. issn. 1674?2869. 2016. 03. 012]
　ZHANG Yunfei,XU Guixiang,LIU Hui,et al.Preparation and Characterization of Urea Formaldehyde Resins Modified by 2， 4， 6-trimethylol Sodium Phenate[J].Journal of Wuhan Institute of Technology,2016,38(3):263-267.[doi:10. 3969/j. issn. 1674?2869. 2016. 03. 012]
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2，4，6-三羟甲基苯酚钠改性脲醛树脂的制备与表征(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
38
期数:
2016年3期
页码:
263-267
栏目:
材料科学与工程
出版日期:
2016-06-22

文章信息/Info

Title:
Preparation and Characterization of Urea Formaldehyde Resins Modified by 2， 4， 6-trimethylol Sodium Phenate
作者:
张云飞; 徐贵祥; 刘　辉; 张　桥
武汉工程大学材料科学与工程学院，湖北 武汉 430074
Author(s):
ZHANG Yunfei;  XU Guixiang;  LIU Hui;  ZHANG Qiao
School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430074, China
关键词:
2; 4; 6-三羟甲基苯酚钠; 脲醛树脂; 胶合强度; 游离甲醛释放
Keywords:
2; 4; 6-trimethylol sodium phenate;  urea formaldehyde resins;  bond strength;  free formaldehyde emission
分类号:
TQ433
DOI:
10. 3969/j. issn. 1674?2869. 2016. 03. 012
文献标志码:
A
摘要:
以苯酚和甲醛为原料， 在强碱条件下制备中间体2，4，6-三羟甲基苯酚钠，产物经核磁氢谱得到确认；在传统三段工艺条件下（碱-酸-碱工艺），制备了不同2，4，6-三羟甲基苯酚钠/尿素（ TMP/ U）摩尔比的低游离甲醛释放的脲醛树脂并研究了TMP/U摩尔比对脲醛树脂的性能的影响. 结果表明， 随着TMP/U摩尔比的增加， 脲醛树脂中的游离甲醛含量明显降低，改性树脂的粘度有所提高. 当TMP/U摩尔比为1∶40时，脲醛树脂的游离甲醛质量分数小于0.01%；脲醛树脂制备过程中各阶段的游离甲醛含量分析表明，TMP对脲醛树脂中游离甲醛的降低主要发生在碱性阶段和第二批尿素加入阶段后期；随着TMP/U摩尔比的增加，NH4Cl/TMPUF体系的pH值逐渐升高. 此外，改性脲醛树脂粘接胶合板的干强度和湿强度都高于参比组，改性脲醛树脂粘接胶合板的游离甲醛释放最低低于1 mg/L.
Abstract:
The intermediate 2, 4, 6-trimethylol sodium phenate （TMP） was synthesized by using phenol and formaldehyde as raw materials under strong alkaline condition, and characterized by 1H-NMR spectrosopy. In addition, series of TMP-urea-formaldehyde （TMPUF） resins with different TMP/U mole ratios were prepared under traditional three step process （alkali-acid-alkali） and their performances were explored. Results showed that the free formaldehyde concentration reduced while the viscosity of TMPUF resin increased with the increase of mole ratio of TMP/U ； when the mole ratio of TMP/U was higher than 1/40, the free formaldehyde mass fraction in TMPUF resin was less than 0.01%. The analysis of the change of free formaldehyde level during each synthesis period of TMPUF resins showed that the reduction of free formaldehyde concentration mainly happened during the alkali stage and after the second addition of urea； furthermore, the pH value of NH4Cl-TMPUF system gradually increased as the mole ratio of TMP/U rose. In addition, the dry strength and wet strength of plywood bonded by modified UF adhesives were better than those by pure UF adhesive, and the lowest value of formaldehyde emission of plywood bonded by modified UF adhesive was less than 1 mg/L.

参考文献/References:

［1］　AYRILMIS N， LEEYK， KWON J H， et al. Formaldehyde emission and VOCs from LVLs produced with three grades of urea-formaldehyde resin modified with nanocellulose ［J］. Building and environment， 2016， 97： 82-87. ［2］　KHAZAEIAN A， ASHORI A， DIZAJ M Y. Suitability of sorghum stalk fibers for production of particleboard ［J］. Carbohydrate polymers， 2015， 120：15-21. ［3］　陆悦， 马培培， 吴石山， 等. 微甲醛含量脲醛树脂的制备［J］. 高分子材料科学与工程， 2013 （2）： 128-130. LU Y， MA P P， WU S S， et al. Preparation of urea formaldehyde resin with micro-content of free formaldehyde［J］. Polymer materials science＆engineering， 2013 （2）： 128-130. ［4］　荣磊， 顾继友， 谭海彦， 等. 多羟甲基苯酚改性脲醛树脂的研究［J］. 中国胶粘剂， 2010 （9）： 37-41. RONG L， GU J Y， TAN H Y， et al. Study on urea formaldehyde resin modified by multi-hydroxymethyl phenol［J］. China adhesives， 2010 （9）： 37-41. ［5］　COSTA N A， MARTINS D， PEREIRA J， et al. 13C NMR study of presence of uron structures in amino adhesives and relation with wood-based panels performance［J］. Journal of applied polymer science， 2013， 130（6）： 4500-4507. ［6］　BORAN S， USTA M， GUMUSKAYA E. Decreasing formaldehyde emission from medium density fiberboard panels produced by adding different amine compounds to urea formaldehyde resin［J］. International journal of adhesion & adhesives， 2011， 31（7）： 674-678. ［7］　ZANETTI M， PIZZI A. Low addition of melamine salts for improved melamine-urea-formaldehyde adhesive water resistance［J］. Journal of applied polymer science， 2003， 88（2）： 287-292. ［8］　HOONG YB， PIZZI A， CHUAH L A， et al. Phenol urea formaldehyde resin copolymer synthesis and its influence on Elaeis palm trunk plywood mechanical performance evaluated by 13C-NMR and MALDI-TOF mass spectrometry ［J］. International journal of adhesion & adhesives， 2015， 63： 117-123. ［9］　CANDAN Z， AKBULUT T. Nano-engineered plywood panels： Performance properties ［J］. Composites part b-engineering， 2014， 64： 155-161. ［10］ TOMITA B， HSE CY. Phenol urea formaldehyde （PUF） co-condensed wood adhesives［J］. International journal of adhesion & adhesives， 1998， 18： 69-79.本文编辑：龚晓宁

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更新日期/Last Update: 2016-06-23