|本期目录/Table of Contents|

[1]陈 瑞,杨 梅,郭 童,等.基于色胺的磷氮阻燃剂的合成及阻燃性能[J].武汉工程大学学报,2022,44(06):648-652.[doi:10.19843/j.cnki.CN42-1779/TQ.202005004]
　CHEN Rui,YANG Mei,GUO Tong,et al.Synthesis and Flame Retardancy of Tryptamine-Containing?Phosphorous-Nitrogen Compound[J].Journal of Wuhan Institute of Technology,2022,44(06):648-652.[doi:10.19843/j.cnki.CN42-1779/TQ.202005004]
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基于色胺的磷氮阻燃剂的合成及阻燃性能(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
44
期数:
2022年06期
页码:
648-652
栏目:
材料科学与工程
出版日期:
2022-12-31

文章信息/Info

Title:
Synthesis and Flame Retardancy of Tryptamine-Containing?Phosphorous-Nitrogen Compound

文章编号:
1674 - 2869（2022）06 - 0648 - 05
作者:
陈 瑞1; 2; 杨 梅1; 郭 童2; 李道远1; 陈国旗1; 王寅嵩*1
1. 皖西学院生物与制药工程学院，安徽 六安 237012；
2. 武汉工程大学化工与制药学院，湖北 武汉 430205
Author(s):
CHEN Rui1; 2; YANG Mei1; GUO Tong2; LI Daoyuan1; CHEN Guoqi1; WANG Yinsong*1
1. School of Biological and Pharmaceutical Engineering，West Anhui University， Lu’an 237012， China；
2. School of Chemical Engineering and Pharmacy，Wuhan Institute of Technology， Wuhan 430205， China

关键词:
环氧树脂; 色胺; 磷杂菲
Keywords:
epoxy resin;  tryptamine;  phosphaphenanthrene
分类号:
O4633
DOI:
10.19843/j.cnki.CN42-1779/TQ.202005004
文献标志码:
A
摘要:
以对羟基苯甲醛、9，10-二氢-9-氧杂-10-磷杂菲-10-氧化物（DOPO）和色胺为原料，成功合成了一种新型阻燃剂——对羟基苯甲色胺磷杂菲（PHTD）。并用其对环氧树脂（EP）进行阻燃性能优化。当PHTD的质量分数达到4%时，EP/PHTD热塑材料的阻燃性能达到V1级别，氧指数（LOI）达到29.2%。在锥形量热实验中，PHTD的添加显著降低了材料的热释放量，幅度达到64.2%。此外，用扫描电子显微镜检测锥形量热测试后的残渣，结果表明，当PHTD的质量分数为8%时，EP/PHTD热塑材料燃烧后的残渣的结构为均匀的致密炭层，可以作为隔绝热、氧的屏障。
Abstract:
This work focuses on a novel flame retardant p-hydroxybenzatryptamine phosphaphenanthrene （PHTD） which is synthesized from tryptamine， p-hydroxybenzaldehyde and 9,10-Dihydro-9-oxa-10-phospha -phenanthrene-10-oxide（DOPO）. The addition of PHTD dramatically improves flame retardancy of epoxy resin （EP）. The flame-retardant thermoset EP/PHTD is qualified a UL-94 V-1 rating and possesses the value of 29.2% in limited oxygen index when the mass fraction of PHTD is 4%. Cone calorimeter test indicates that the release of heat decreases by 64.2% due to the introduction of PHTD. The residue after cone calorimeter test was also analyzed by scanning electron microscopy. The result shows when the mass fraction of PHTD is 8%， char residue for EP/PHTD thermoset is homogeneous and compact ，and the cross-linked layer acts as a positive barrier for exchange of heat and oxygen.

参考文献/References:

［1］ TANG H，ZHU Z M，CHEN R，et al. Synthesis of DOPO-based pyrazine derivative and its effect on flame retardancy and thermal stability of epoxy resin ［J］. Polymers for Advanced Technologies，2019，30（9）：2331-2339.

［2］ LIANG S Y， NEISUIS N M， GAAN S. Recent developments in flame retardant polymeric coatings ［J］. Progress in Organic Coatings，2013，76（11）：1642-1665.
［3］ ZHU Z M，WANG L X，DONG L P. Influence of a novel P/N-containing oligomer on flame retardancy and thermal degradation of intumescent flame-retardant epoxy resin ［J］. Polymer Degradation and Stability，2019，162：129-137.
［4］ SADEZKY A， MUCKENHUBER H， GROTHE H，et al. Raman microspectroscopy of soot and related carbonaceous materials：spectral analysis and structural information ［J］. Carbon，2005，43（8）：1731-1742.
［5］ CHEN R， HU K X， TANG H， et al. A novel flame retardant derived from DOPO and piperazine and its application in epoxy resin：flame retardance，thermal stability and pyrolysis behavior ［J］. Polymer Degradation and Stability，2019，166：334-343.
［6］ ZHANG T，LIU W S，WANG M X，et al. Synergistic effect of an aromatic boronic acid derivative and magnesium hydroxide on the flame retardancy of epoxy resin ［J］. Polymer Degradation and Stability，2016，130：257-263.
［7］ SHEN D，XU Y J，LONG J W，et al. Epoxy resin flame-retarded via a novel melamine-organophosphinic acid salt：thermal stability，flame retardance and pyrolysis behavior ［J］. Journal of Analytical and Applied Pyrolysis，2017，128：54-63.
［8］ YANG S， WANG J， HUO S Q， et al. Synthesis of a phosphorus/nitrogen-containing compound based on maleimide and cyclotriphosphazene and its flame-retardant mechanism on epoxy resin ［J］. Polymer Degradation and Stability，2016，123：9-16.
［9］ QIU Y， LIU Z， QIAN L J，et al. Pyrolysis and flame retardant behavior of a novel compound with multiple phosphaphenan-threne groups in epoxy thermosets ［J］. Journal of Analytical and Applied Pyrolysis，2017，127：23-30.
［10］ JIAN R K，WANG P，DUAN W S，et al. Synthesis of a novel P/N/S-containing flame retardant and its application in epoxy resin：thermal property，flame retardance and pyrolysis behavior ［J］. Industrial and Engineering Chemistry Research，2016，55（44）：11520-11527.
［11］ ZANG L，WAGNER S，CIESIESKI M，et al. Novel star-shaped and hyperbranched phosphorus containing flame retardants in epoxy resins ［J］. Polymers for Advanced Technologies，2011，22（7）：1182-1191.
［12］ XIONG Y Q， JIANG Z J， XIE Y Y， et al. Development of a DOPO-containing melamine epoxy hardeners and its thermal and flame-retardant properties of cured products ［J］. Journal of Applied Polymer Science，2013，127（6）：4352-4358.
［13］ BUCZKO A，STELZIG T，BOMMER L，et al. Bridged DOPO derivatives as flame retardants for PA6 ［J］. Polymer Degradation and Stability，2014，107：158-165.
［14］ ZHU Z M，LIN P L，WANG H，et al. A facile one-step synthesis of highly efficient melamine salt reactive flame retardant for epoxy resin ［J］. Journal of Materials Science，2020，55（27）：12836-12847.
［15］ JIN S L，QIAN L J，QIU Y，et al. High-efficiency flame retardant behavior of bi-DOPO compound with hydroxyl group on epoxy resin [J]. Polymer Degradation and Stability，2019，166：344-352.
［16］ CHEN R， LUO Z J， YU X J， et al. Synthesis of chitosan-based flame retardant and its fire resistance in epoxy resin ［J］. Carbohydrate Polymers，2020，245：116530：1-7.

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备注/Memo

备注/Memo:
收稿日期：2020-05-05
基金项目：安徽省自然科学基金（KJ103762015B17）；武汉工程大学第十四届校长基金（2019008）
作者简介：陈 瑞，博士，实验师。E-mail：[email protected]
*通讯作者：王寅嵩，学士，讲师。E-mail：[email protected]
引文格式：陈瑞，杨梅，郭童，等. 基于色胺的磷氮阻燃剂的合成及阻燃性能［J］. 武汉工程大学学报，2022，44（6）：648-652，669.

更新日期/Last Update: 2023-01-08