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[1]胡亏全,朱怀锐,刘琼,等.水合二氧化钛吸附与除铁影响因素[J].武汉工程大学学报,2013,(09):13-17.[doi:103969/jissn16742869201309003]
 HU Kui\|quan,ZHU Huai\|rui,LIU Qiu,et al.Influencing factors of adsorption and removing ferrous ion of hydrated titanium[J].Journal of Wuhan Institute of Technology,2013,(09):13-17.[doi:103969/jissn16742869201309003]
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水合二氧化钛吸附与除铁影响因素(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2013年09期
页码:
13-17
栏目:
资源与土木工程
出版日期:
2013-10-10

文章信息/Info

Title:
Influencing factors of adsorption and removing ferrous ion of hydrated titanium
文章编号:
16742869(2013)09001305
作者:
胡亏全1朱怀锐1刘琼2艾秋红2伍向阳1
1. 湖北驰顺化工有限公司,湖北 黄石 435200;2. 湘潭大学化工学院,湖南 湘潭 411100
Author(s):
HU Kui\|quan1 ZHU Huai\|rui1 LIU Qiu2 AI Qiong\|hong2 WU Xiang\|yang1
1. Hubei Chishun Chemical Co, Ltd, Huangshi 435200,China; 2. School of Chemical, Xiangtan University, Xiangtan 411100,China
关键词:
水合二氧化钛亚铁离子吸附水洗
Keywords:
bydrated titanium ferrous ion adsorption washing
分类号:
TQ028.5
DOI:
103969/jissn16742869201309003
文献标志码:
A
摘要:
为探究水合二氧化钛对亚铁离子的吸附平衡与吸附动力学,通过静态吸附实验,研究了吸附平衡时间、亚铁离子浓度、吸附硫酸质量浓度和温度对水合二氧化钛吸附亚铁离子的影响;通过真空抽滤洗涤实验考察了洗水硫酸质量浓度和温度对洗涤过程中铁去除率的影响.结果表明,水合二氧化钛吸附亚铁离子的平衡吸附时间为9 h,亚铁离子初始浓度最佳为300 mg/L, 硫酸质量浓度的增加和温度的升高均不利于水合二氧化钛对亚铁离子的吸附;吸附动力学符合一级动力学 Lagergren 方程,吸附等温方程符合Freundlich方程;洗涤过程中洗水的温度升高和洗水的硫酸质量浓度提高均利于亚铁离子的去除.
Abstract:
To explore the hydrated titania on ferrous ions adsorption equilibrium and adsorption kinetics, the effect of the adsorption equilibrium time, initial concentration of ferrous ions, acidity and temperature on hydrated titanium dioxide adsorbing ferrous ion was studied by the static adsorption experiment and suction filter washing experiment. Meanwhile, the effect of acidity and temperature of washing water on iron removal rate in the washing process was also studied. The results indicated that the adsorption equilibrium time of hydrated titanium dioxide adsorbing ferrous ions is 9 hours, and the best of initial concentration of ferrous ions is 300 mg/L; the adsorption kinetics accords with first order kinetics equation of Lagergren, and the adsorption isotherm equation accords with Freundlich equation; the increasing of temperature and acidity is unfavorable for hydrated titanium dioxide adsorbing ferrous ions; increasing the temperature and acidity of washing water in the washing process increases the iron removal rate.

参考文献/References:

[1]张益都.硫酸法钛白粉生产技术创新[M].北京:北京化学工业出版社,2010. ZHANG Yi\|du. Production technology of Titanium dioxide have a Innovation by sulfuric acid method[M]. Beijing: Beijing Chemical Industry Press,2010.(in Chinese).[2]Rao M M,ramesh A,Rao G P C,et al. Removal of copper and cadmium from the aqueous solutions by activated carbon derived from Ceiba pentandra hulls[J].Journal of Hazardous Materials, 2006,129:123\|129.[3]Onganer Y,Temur C. Adsorption dynamics of Fe(III) from aqueous solution onto activated carbon [J].J Colloid Intergsce Sci, 1998,205:241\|244.[4]彭丽霞,王建晨,文明芬,等. 球形复合无机离子交换剂水合氧化钛\|硅钛酸钠的制备及性能研究[J].离子交换与吸附,2005,21(6):487\|492.PENG Li\|xia, WANG Jian\|chen, WEN Ming\|fen ,et al. Study on the preparation and properties of spherical composite ion exchanger HTO\|NaTS[J]. Ion Exchange and Adsorption ,2005,21(6):487\|492(in Chinese).[5]藏春梅,张改莲,孙兆祥.水合二氧化钛\|磷钼酸铵微球复合无机离子交换剂的合成[J]. 离子交换与吸附,2000,16(5):406\|412.ZANG Chun\|mei, ZHANG Gai\|lian.SUN Zhao\|xiang. Structure and properties of hydrated titanium dioxide\|ammonium molbdophosphate spherical comples inorganic ion exchanger [J].Ion Exchange and Adsorption,2000,16(5):406\|412. (in Chinese).[6]程昌敬,刘东,张嫦 .羧甲基化壳聚糖修饰磁性硅粒子去除Cr(Ⅵ)离子[J].化工进展,2012,31(1):227\|232.CHENG Chang\|jing, LIU Dong ,ZHANG Chang. Adsorptive removal of Cr(Ⅵ) ions by carboxymethylated\|chitosan modified magnetic silica particles[J].Progress of Chemical,2012,31(1):227\|232. (in Chinese).

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备注/Memo

备注/Memo:
收稿日期:20130903作者简介:胡亏全(1973\|),男,湖北监利人,工程师.研究方向:农药化学.
更新日期/Last Update: 2013-10-11